Structured document retrieval aims at retrieving the document components that best satisfy a query, instead of merely retrieving pre-defined document units. This paper reports on an investigation of a tf-idf-acc approach, where tf and idf are the classical term frequency and inverse document frequency, and acc, a new parameter called accessibility, that captures the structure of documents. The tf-idf-acc approach is defined using a probabilistic relational algebra. To investigate the retrieval quality and estimate the acc values, we developed a method that automatically constructs diverse test collections of structured documents from a standard test collection, with which experiments were carried out. The analysis of the experiments provides estimates of the acc values